India have gone in with three all-rounders including two spinners in Jadeja and Sundar.
The young Sai Sudharsan is left out after playing just one Test, with Karun Nair expected to take his place at No 3.
Interestingly, India have still not included left-arm wrist spinner Kuldeep Yadav as they preferred Sundar to add depth to the lower order batting.
'We were tempted to play Kuldeep but decided to add some depth to the batting,' said Gill at the toss.
India have as many as six bowling options in Siraj, Prasidh, Akash Deep, Jadeja, Sundar and Reddy.
Check out the playing XIs:
England: Zak Crawley, Ben Duckett, Ollie Pope, Joe Root, Harry Brook, Ben Stokes (captain), Jamie Smith (w/k), Chris Woakes, Brydon Carse, Josh Tongue, Shoaib Bashir.
India: Yashasvi Jaiswal, K L Rahul, Karun Nair, Shubman Gill (captain), Rishabh Pant (w/k), Nitish Kumar Reddy, Ravindra Jadeja, Washington Sundar, Akash Deep, Mohammed Siraj, Prasidh Krishna.