The 173rd-ranked Indian lost 6-2, 1-6, 4-6 to the 164th-ranked Jurgen Zopp of Estonia.
World No. 168 Saketh Myneni is the last Indian standing, having edged out compatriot and Chennai Open quarter-finalist Ramkumar Ramanathan 6-4, 6-1.
Myneni will next face 261st-ranked Italian Lorenzo Giustino on Friday for a place in the final round of qualifying at the year’s first Grand Slam.
- Sania-Martina win 29th consecutive match, break 22-year-old record
Image: Somdev Devvarman
Sania maintains top spot, Bopanna ninth in doubles rankings
Chennai Open: Wild carder Ramkumar marches on but Somdev knocked out
Somdev rallies to qualify for Chennai Open main draw
Ramkumar wins hearts in defeat, Wawrinka in semis
Ramkumar rallies into Chennai Open quarterfinals