A tired looking Maria Sharapova bowed out of the third round of the $6.6 million China Open on Wednesday, beaten 6-2, 6-4 by China's Peng Shuai to the delight of the crowd at the Olympic tennis centre.
However, there was to be no fight back from the former world number one Wednesday and Peng upset a high profile player for the second evening in a row after her second round win over defending champion Jelena Jankovic.
Peng must next beat either second seed Serena Williams or Nadia Petrova for a place in the China Open semi-finals for the third time.
Svetlana Kuznetsova, the 2006 China Open champion, overcame a stuttering serve to claim her place in the last eight with a 6-3, 5-7, 6-0 victory over Ukraine's Alona Bodarenko.
The sixth seeded Russian will face compatriot Anastasia Pavlyuchenkova in the quarter-finals after the teen-ager beat Canadian Aleksandra Wozniak 6-4, 6-4.
Men's fourth seed Nikolay Davydenko earlier boosted his chances of reaching the ATP Tour's season finale for a fifth time with a 6-1, 6-0 thrashing of Philipp Kohlschreiber.
The workaholic Russian, who won his third title of the year in Kuala Lumpur last weekend, wasted no time in dispensing with the 22nd-ranked German to reach the quarter-finals.
The world number eight reached the final of the last version of the Masters Cup in Shanghai last year and needs a good result in Beijing to stay in contention for one of three remaining places in the new season-ending World Tour Finals in London.
Davydenko will meet Croatian Marin Cilic in the quarter-finals after the eighth seed beat France's Julien Benneteau 6-2, 2-6, 6-0 earlier Wednesday.
Second seed Novak Djokovic takes on fellow Serbian Viktor Troicki in the final match of the day on centre court.
Kuznetsova upset, Mauresmo injured
Petrova strolls, Pennetta struggles
Safina beats Kuznetsova, in final
Spotted: Nadia Petrova in Sydney
Jankovic wins Beijing Open