Nathalie Dechy stunned U.S. Open champion Svetlana Kuznetsova 3-6, 7-6, 8-6 in the opening singles of the Fed Cup final on Saturday to give champions France a 1-0 lead against hot favourites Russia.
Dechy, the highest-ranked non-Russian player at number 21, battled back in the second set to force a tiebreak, which she won 7-4.
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The Russians are bidding to win their first Fed Cup title and are favourites against a French team missing world number two Amelie Mauresmo and twice grand slam champion Mary Pierce.
French Open champion Anastasia Myskina will hope to level the score for the hosts when she takes on Moscow-born 16-year-old Tatiana Golovin in the second singles later.