Biographer Jenny Paul has claimed in his new work that the Rolling Stones lead was married to his now ex-wife, model Jerry Hall, when the Original Sin actress paired up with him.
Apparently, they first began seeing each other after Jolie appeared in The Rolling Stones video Anybody Seen My Baby? in 1997.
They even had a second affair in 2003, reports the Daily Telegraph.
Paul has researched and written the book over the course of six years.
Photograph: Jason Reed/Mike Cassese/Reuters
Does SRK look like Mick or Mike?
Urmila gives award to Van Damme
What Angelina Jolie wanted
World's most expensive wedding singers
Michael Jordan inducted into Basketball Hall of Fame