In an exclusive, tell-all interview to Vogue magazine, the actress has spilt the beans on Brad Pitt, and her relationship with the actor.
Unlike what rumours had fans believing, the actress makes it clear that she and Pitt were not involved during the filming of Mr & Mrs Smith.
'I think we were both the last two people who were looking for a relationship. I certainly wasn't. I was quite content to be a single mom,' Jolie tells the magazine.
'Because of the film we ended up being brought together to do all these crazy things, and I think we found this strange friendship and partnership that kind of just suddenly happened,' she says.
Jolie remained 'very, very good friends' with Pitt after shooting ended, she says. 'And then life developed in a way where we could be together, where it felt like something we would do, we should do.'
Don't expect the twice-divorced Jolie, 31 and Pitt, 42, to suddenly up and get married, the actress warns. 'We are legally bound to our children, not to each other, and I think that's the most important thing,' the actress is quoted in Vogue.
In the picture, the couple look content at the premiere of Jolie's new film, The Good Shepherd, in New York on Monday December 11.
Photograph: Getty Images