The couple -- known as Brangelina, has ended Tom Cruise and Jennifer Aniston's reign, reports the Mirror.
According to the Guinness Book of World Records, Brangelina have hit the pinnacle by a combination of Internet searches, press stories and earnings.
Meanwhile, Samuel L. Jackson has been named the highest-earning actor for the 68 films he has taken part in over the years, raking in 4.1 billion pounds at the box office.
Director Tim Burton and actor Johnny Depp have become the most lucrative Hollywood partnership, grossing 550 million pounds from six movies.
Other new records include the Sugababes' hit About You Now -- the first to get to No1 in the charts just on net download sales.
Text: ANI | Photograph: Getty Images